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Bimetallic amine-bridged bis(phenolate) lanthanide aryloxides and alkoxides: synthesis, characterization, and application in the ring-opening polymerization of rac -lactide and rac -β-butyrolactone

Nie, Kun ; Feng, Tao ; Song, FengKui ; Zhang, Yong ; Sun, HongMei ; Yuan, Dan ; Yao, YingMing ; Shen, Qi

Science China Chemistry, 2014, Vol.57(8), pp.1106-1116 [Tạp chí có phản biện]

ISSN: 1674-7291 ; E-ISSN: 1869-1870 ; DOI: 10.1007/s11426-014-5142-7

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  • Nhan đề:
    Bimetallic amine-bridged bis(phenolate) lanthanide aryloxides and alkoxides: synthesis, characterization, and application in the ring-opening polymerization of rac -lactide and rac -β-butyrolactone
  • Tác giả: Nie, Kun ; Feng, Tao ; Song, FengKui ; Zhang, Yong ; Sun, HongMei ; Yuan, Dan ; Yao, YingMing ; Shen, Qi
  • Chủ đề: amine-bridged bis(phenolate) ligand ; bimetallic lanthanide aryloxides and alkoxides ; ring-opening polymerization ; stereoselectivity
  • Là 1 phần của: Science China Chemistry, 2014, Vol.57(8), pp.1106-1116
  • Mô tả: A series of neutral bimetallic lanthanide aryloxides p -C 6 H 4 [OLnL(THF) n ] 2 [Ln = Y ( 1 ), Yb ( 2 ), Sm ( 3 ) ( n = 1) and La ( 4 ) ( n = 2), L = Me 2 NCH 2 CH 2 N{CH 2 -(2-O-C 6 H 2 - t Bu 2 -3,5)} 2 ] and alkoxides p -C 6 H 4 CH 2 [OLnL(THF)] 2 [Ln = Y ( 5 ), Yb ( 6 )] supported by an amine-bridged bis(phenolate) ligand have been synthesized through one-pot reactions of Ln(C 5 H 5 ) 3 (THF), LH 2 with p -benzenediol and 1,4-benzenedimethanol, respectively. All complexes have been fully characterized by elemental analyses, single-crystal X-ray diffraction analysis, and IR and multi-nuclear NMR spectroscopy (in the cases of 1 , 4 and 5 ). Study of their catalytic behavior revealed that, in general, all complexes are efficient initiators for the polymerization of rac -lactide (LA) and rac -β-butyrolactone (BBL), except for 3 and 4 in the case of BBL. The influence imposed by lanthanides of different ionic radii and initiating groups of different structures on the activity, controllability, and stereoselectivity of polymerization were systematically studied and compared. Highly heterotactic PLA ( P r up to 0.99) and syndiotactic PHB ( P r ≈ 0.81) with high molecular weight and narrow polydispersity formed and were automatically capped with hydroxyl functionality at both ends.
  • Ngôn ngữ: English
  • Số nhận dạng: ISSN: 1674-7291 ; E-ISSN: 1869-1870 ; DOI: 10.1007/s11426-014-5142-7

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