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The metal-solution interface

Schmickler, Wolfgang ; Santos, Elizabeth

ISBN: 9783642049361 ; ISBN: 3642049362 ; E-ISBN: 9783642049378 ; E-ISBN: 3642049370 ; DOI: 10.1007/978-3-642-04937-8_5

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  • Nhan đề:
    The metal-solution interface
  • Tác giả: Schmickler, Wolfgang ; Santos, Elizabeth
  • Chủ đề: Chemistry ; Electrochemistry ; Surfaces and Interfaces, Thin Films ; Chemistry
  • Mô tả: The interface between a metal and an electrolyte solution is the most important electrochemical system, and we begin by looking at the simplest case, in which no electrochemical reactions take place. The system we have in mind consists of a metal electrode in contact with a solution containing inert, nonreacting cations and anions. A typical example would be the interface between a silver electrode and an aqueous solution of KF. We further suppose that the electrode potential is kept in a range in which no or only negligible decomposition of the solvent takes place – in the case of an aqueous solution, this means that the electrode potential must be below the oxygen evolution and above the hydrogen evolution region. Such an interface is said to be ideally polarizableideally polarizable , a terminology based on thermodynamic thinking. The potential range over which the system is ideally polarizable is known as the potential windowpotential window , since in this range electrochemical processes can be studied without interference by solvent decomposition.
  • Nơi xuất bản: Berlin, Heidelberg: Springer Berlin Heidelberg
  • Năm xuất bản: 2010
  • Ngôn ngữ: English
  • Số nhận dạng: ISBN: 9783642049361 ; ISBN: 3642049362 ; E-ISBN: 9783642049378 ; E-ISBN: 3642049370 ; DOI: 10.1007/978-3-642-04937-8_5

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